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Analysis of institutional authors

Marzo L.Corresponding AuthorAlemán J.Corresponding Author

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April 18, 2022
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Remote Giese Radical Addition by Photocatalytic Ring Opening of Activated Cycloalkanols

Publicated to:ADVANCED SYNTHESIS & CATALYSIS. 364 (10): 1689-1694 - 2022-05-17 364(10), DOI: 10.1002/adsc.202200220

Authors: Salaverri N; Carli B; Gratal PB; Marzo L; Alemán J

Affiliations

Univ Autonoma Madrid, Ctr Innovat Adv Chem ORFEO CINQA, Madrid 28049, Spain - Author
Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, Madrid 28049, Spain - Author
Univ Autonoma Madrid, Organ Chem Dept, Modulo 1, Madrid 28049, Spain - Author
Universidad Autónoma de Madrid - Author

Abstract

The application of proton coupled electron transfer (PCET) processes in organic synthesis has opened the door to new radical intermediates for synthesis such as alkyl radicals in remote positions to a ketone. Herein, we present the addition of these remote alkyl radicals to electron deficient double bonds under photoorganocatalyzed and very mild conditions. The method is not only applicable to diactivated double bonds, but monoactivated ones are also accessible using more stabilized alkyl radicals, and alkyl chains of any length can be introduced. The final products can be easily converted into more complex structures via a one-pot process, and the activating functional groups were transformed in the more versatile methyl esters. Mechanistic investigations support a mechanistic proposal based on a PCET process. (Figure presented.).

Keywords

pcetphotocatalysisphotoredox catalysisvisible lightC bond-cleavageGiese radical additionPcetPhotocatalysisVisible light

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal ADVANCED SYNTHESIS & CATALYSIS due to its progression and the good impact it has achieved in recent years, according to the agency WoS (JCR), it has become a reference in its field. In the year of publication of the work, 2022, it was in position 4/52, thus managing to position itself as a Q1 (Primer Cuartil), in the category Chemistry, Organic. Notably, the journal is positioned above the 90th percentile.

From a relative perspective, and based on the normalized impact indicator calculated from World Citations from Scopus Elsevier, it yields a value for the Field-Weighted Citation Impact from the Scopus agency: 1.03, which indicates that, compared to works in the same discipline and in the same year of publication, it ranks as a work cited above average. (source consulted: ESI Nov 14, 2024)

This information is reinforced by other indicators of the same type, which, although dynamic over time and dependent on the set of average global citations at the time of their calculation, consistently position the work at some point among the top 50% most cited in its field:

  • Field Citation Ratio (FCR) from Dimensions: 3.71 (source consulted: Dimensions Aug 2025)

Specifically, and according to different indexing agencies, this work has accumulated citations as of 2025-08-08, the following number of citations:

  • WoS: 1
  • Scopus: 9

Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2025-08-08:

  • The use, from an academic perspective evidenced by the Altmetric agency indicator referring to aggregations made by the personal bibliographic manager Mendeley, gives us a total of: 10.
  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 10 (PlumX).

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

  • The Total Score from Altmetric: 12.85.
  • The number of mentions on the social network X (formerly Twitter): 17 (Altmetric).
  • The number of mentions on Wikipedia: 1 (Altmetric).

It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

  • The work has been submitted to a journal whose editorial policy allows open Open Access publication.
  • Assignment of a Handle/URN as an identifier within the deposit in the Institutional Repository: https://repositorio.uam.es/handle/10486/703079

Leadership analysis of institutional authors

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Salaverri N) and Last Author (ALEMAN LARA, JOSE JULIAN).

the authors responsible for correspondence tasks have been MARZO PUERTA, LEYRE and ALEMAN LARA, JOSE JULIAN.