{rfName}
Tu

Indexed in

License and use

Citations

Altmetrics

Grant support

Financial support from the Spanish MCIN/AEI/10.13039/501100011033 and European Union NextGenerationEU/PRTR (TED2021-131255B-C43), MCIU/AEI/10.13039/501100011033/FEDER, UE (PID) (PID2023-151167NB-I00, PID2021-122882NB-I00, PID2021-126132NB-I00 and PID2023-150255NB-I00), the Comunidad de Madrid and the Spanish State through the Recovery, Transformation and Resilience Plan ["Materiales Disruptivos Bidimensionales (2D)" (MAD2D-CM) (UAM1)-MRR Materiales Avanzados], the Gobierno de Aragon- FSE (E47_23R-research group), the Basque Government project IT1458-22, and the European Union through the Next Generation EU funds is fully acknowledged. IMDEA Nanociencia acknowledges support from the "Severo Ochoa" Programme for Centres of Excellence in R&D (MINECO, CEX2020-001039-S). INMA acknowledges support from the "Severo Ochoa" Programme for Centres of Excellence in R&D (MCIN, CEX2023-001286-S). E. L. S. acknowledges MECD, Spain, for a F. P. U. Fellowship.

Analysis of institutional authors

López-Serrano, ElisaAuthorTorres, TomasCorresponding Author

Share

June 9, 2025
Publications
>
Article
Hybrid Gold

Tuning the liquid crystal behavior of subphthalocyanines: effects of substitution, chirality, and hydrogen bonding

Publicated to:JOURNAL OF MATERIALS CHEMISTRY C (): - - 2025-05-27 (), DOI: 10.1039/d5tc01417d

Authors: Labella J; López-Serrano E; Labrador-Santiago J; Barberá J; Folcia CL; Sierra T; Torres T

Affiliations

IMDEA Nanociencia, Campus Cantoblanco, Madrid 28049, Spain - Author
Kyoto Univ Katsura, Dept Mol Engn, Kyoto 6158510, Japan - Author
Univ AutOnoma Madrid, Dept Organ Chem, Campus Cantoblanco,C Francisco Tomas & Valiente 7, Madrid 28049, Spain - Author
Univ Autonoma Madrid, Inst Adv Res Chem Sci IAdChem, Madrid 28049, Spain - Author
Univ Basque Country, Fac Sci & Technol, Dept Phys, Bilbao 48940, Spain - Author
Univ Zaragoza, Fac Ciencias, Dept Quim Organ, Zaragoza 50009, Spain - Author
Univ Zaragoza, Inst Nanociencia & Mat Aragon INMA, CSIC, Zaragoza 50009, Spain - Author
See more

Abstract

Bowl-shaped aromatics that self-assemble into columnar liquid crystals (LCs) are key components for developing polarized semiconductors. However, progress in this field has been sluggish, as the limited set of available pi-conjugated curved scaffolds has left structure-property relationships poorly understood. Herein the role that substitution pattern, substituent nature, and chirality play in the LC columnar organization of subphthalocyanines (SubPcs) is explored. Remarkably, it is revealed that enantiopure SubPcs exhibit a reduced tendency to form LC phases compared to their racemic counterparts, whereas higher substitution density increases flexibility within the columns, compromising coaxial alignment. Moreover, we find that the use of conformationally flexible, pi-extended peripheral substituents enables efficient pi-pi stacking, and that the incorporation of hydrogen-bonding amide groups leads to highly stable mesophases with elevated melting points, although the mesophase remains at room temperature after thermal treatment. These trends are further rationalized through theoretical modeling. Overall, this work provides valuable synthetic and design guidelines for advancing bowl-shaped aromatics toward next-generation functional columnar liquid crystals.

Keywords

Quality index

Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2025-07-09:

With a more dissemination-oriented intent and targeting more general audiences, we can observe other more global scores such as:

  • The Total Score from Altmetric: 4.6.
  • The number of mentions on the social network X (formerly Twitter): 9 (Altmetric).

It is essential to present evidence supporting full alignment with institutional principles and guidelines on Open Science and the Conservation and Dissemination of Intellectual Heritage. A clear example of this is:

  • The work has been submitted to a journal whose editorial policy allows open Open Access publication.

Leadership analysis of institutional authors

This work has been carried out with international collaboration, specifically with researchers from: Japan.

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: First Author (Labella, Jorge) and Last Author (TORRES CEBADA, TOMAS).

the authors responsible for correspondence tasks have been Labella, Jorge and TORRES CEBADA, TOMAS.