{rfName}
Se

Indexed in

Altmetrics

Analysis of institutional authors

Greciano, E EAuthorValera, J SAuthorPrieto, PCorresponding Author

Share

July 2, 2024
Publications
>
Article
No

Self-assembly of T-shape 2H-benzo[d][1,2,3]triazoles. Optical waveguide and photophysical properties

Publicated to: RSC Advances. 6 (43): 36544-36553 - 2016-01-01 6(43), DOI: 10.1039/c6ra02473d

Authors:

Torres, I; Carrillo, J R; Diaz-Ortiz, A; Martin, R; Gomez, M V; Stegemann, L; Strassert, C A; Orduna, J; Buendia, J; Greciano, E E; Valera, J S; Matesanz, E; Sanchez, L; Prieto, P
[+]

Affiliations

Univ Castilla La Mancha, Fac Ciencias & Tecnol Quim, Dept Q Inorgan Q Organ & Bioquim, E-13071 Ciudad Real, Spain - Author
Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Organ, E-28040 Madrid, Spain - Author
Univ Munster, Ctr Nanotechnol CeNTech, Heisenbergstr 11, D-48149 Munster, Germany - Author
Univ Munster, Inst Phys, Heisenbergstr 11, D-48149 Munster, Germany - Author
Univ Zaragoza, CSIC, Dept Quim Organ, Fac Ciencias,Inst Ciencias Mat Aragon, E-50009 Zaragoza, Spain - Author
See more

Abstract

T-Shaped 2H-benzo[d][1,2,3]triazole derivatives have been synthesized by Sonogashira coupling reactions under microwave irradiation. DFT calculations were performed in order to understand the structure-property relationships - an aspect that is of vital importance for the rational design of organic self-assemblies for optoelectronic applications. Concentration-dependent H-1 Pulse Field-Gradient Spin-Echo (PFGSE) NMR spectroscopy and UV/Vis spectrophotometry indicated the absence of a tendency for the aggregation of single molecules in solution. In contrast, in the solid state these compounds form organized aggregates and these were studied by scanning electron microscopy (SEM), which showed the influence that the peripheral substitution has on the morphology of the aggregates. For example, methoxy-substituted benzotriazoles self-assemble into thick and crystalline needle-like structures. However, the unsubstituted triazoles give rise to flower-like aggregates. Interestingly, the aggregates formed by benzotriazole 1c exhibit waveguide properties.
[+]

Keywords

Building-blocksElectronic-propertiesEnergieGaussian-type basisMolecular-orbital methods

Quality index

Bibliometric impact. Analysis of the contribution and dissemination channel

The work has been published in the journal RSC Advances due to its progression and the good impact it has achieved in recent years, according to the agency Scopus (SJR), it has become a reference in its field. In the year of publication of the work, 2016, it was in position , thus managing to position itself as a Q1 (Primer Cuartil), in the category Chemical Engineering (Miscellaneous). Notably, the journal is positioned above the 90th percentile.

From a relative perspective, and based on the normalized impact indicator calculated from World Citations from Scopus Elsevier, it yields a value for the Field-Weighted Citation Impact from the Scopus agency: 1.04, which indicates that, compared to works in the same discipline and in the same year of publication, it ranks as a work cited above average. (source consulted: ESI Nov 13, 2025)

Specifically, and according to different indexing agencies, this work has accumulated citations as of 2026-01-20, the following number of citations:

  • WoS: 28
  • Scopus: 29
[+]

Impact and social visibility

From the perspective of influence or social adoption, and based on metrics associated with mentions and interactions provided by agencies specializing in calculating the so-called "Alternative or Social Metrics," we can highlight as of 2026-01-20:

  • The use of this contribution in bookmarks, code forks, additions to favorite lists for recurrent reading, as well as general views, indicates that someone is using the publication as a basis for their current work. This may be a notable indicator of future more formal and academic citations. This claim is supported by the result of the "Capture" indicator, which yields a total of: 22 (PlumX).
[+]

Leadership analysis of institutional authors

This work has been carried out with international collaboration, specifically with researchers from: Germany.

There is a significant leadership presence as some of the institution’s authors appear as the first or last signer, detailed as follows: Last Author (PRIETO RECIO, MARIA PILAR).

the author responsible for correspondence tasks has been PRIETO RECIO, MARIA PILAR.

[+]

Awards linked to the item

Financial support from the MINECO of Spain (projects CTQ2012-35692 and CTQ2014-52331-R), Junta de Comunidades de Castilla-La Mancha (FEDER funded project PEII-2014-002-A), and DFG (SFG-TRR 61, project C07) is gratefully acknowledged. I. Torres and R. Martin are indebted to MEC for a FPU studentship. M. V. G. thanks the MINECO of Spain for funding her contract through the Ramon y Cajal program and Parque Cientifico y Tecnologico de Castilla-La Mancha. Moreover, the technical support from High Performance Computing Service of University of Castilla-La Mancha is gratefully acknowledged.
[+]